Packet 11: Bonus 12
The Davies-Green-Mingos rules predict the regiochemistry of nucleophilic addition to these compounds. For 10 points each,
[10m] Name these compounds which bind to a metal center in coordination complexes.
ANSWER: ligands
[10e] Chemists often consider the denticity of ligands, or how many atoms in a ligand coordinate to the metal center. This number, the denticity of EDTA, also happens to be the atomic number of carbon.
ANSWER: six
[10h] This word names an effect in which ligands especially in square planar complexes are more labile towards ligand substitution. This word names the E isomer of an alkene.
ANSWER: trans [or trans effect]
<Science - Chemistry, Rohan Ganeshan> | VAULT II Packet 11
| Heard | PPB | E % | M % | H % |
|---|---|---|---|---|
| 22 | 19.55 | 96% | 82% | 18% |
Conversion
| Team | Opponent | Part 1 | Part 2 | Part 3 | Total | Parts |
|---|---|---|---|---|---|---|
| Lexington A | Belmont B | 10 | 10 | 10 | 30 | MEH |
| Mansfield A | Mansfield B | 0 | 10 | 0 | 10 | E |
| Waltham A | Belmont A | 10 | 0 | 0 | 10 | M |
| Waltham B | Lexington B | 0 | 10 | 0 | 10 | E |
Summary
| Tournament | Edition | Match | Heard | PPB | E % | M % | H % |
|---|---|---|---|---|---|---|---|
| VAULT II at Georgia Tech | 2026-01-24 | ✓ | 6 | 21.67 | 100% | 100% | 17% |
| VAULT II at UCSB | 2026-03-13 | ✓ | 4 | 20.00 | 100% | 100% | 0% |
| VAULT II at Harvard | 2026-04-30 | ✓ | 4 | 15.00 | 75% | 50% | 25% |
| VAULT II Stanford Online | 2026-07-17 | ✓ | 8 | 20.00 | 100% | 75% | 25% |