Packet 1: Bonus 20
Deficiency in the ALA Synthase enzyme that catalyzes the synthesis of these molecules results in X-linked sideroblastic anemia. For 10 points each,
[10h] Name these molecules consisting of four pyrrole rings that serve as a tetradentate ligand for many metals.
ANSWER: porphyrins [prompt on but DO NOT REVEAL chlorophyll or heme with “What general class of molecules does it belong to?”]
[10e] A porphyrin ring surrounds the central iron atom in this protein that carries oxygen in red blood cells.
ANSWER: hemoglobin
[10m] The Rothenmund reaction, a clever way to synthesize porphyrins, reacts pyrrole with this functional group. These terminal carbonyls produce a silver mirror in Tollens’ test.
ANSWER: aldehyde [accept aldoses]
<Science - Biology, Rohan Ganeshan> | VAULT II Packet 01
| Heard | PPB | E % | M % | H % |
|---|---|---|---|---|
| 28 | 15.71 | 100% | 39% | 18% |
Conversion
| Team | Opponent | Part 1 | Part 2 | Part 3 | Total | Parts |
|---|---|---|---|---|---|---|
| Chapel Hill A | Cary Academy | 0 | 10 | 0 | 10 | E |
| East Chapel Hill | Chapel Hill B | 10 | 10 | 0 | 20 | HE |
| Tantaene Animis Caelestibus Irae | Grimsley | 0 | 10 | 0 | 10 | E |
Summary
| Tournament | Edition | Match | Heard | PPB | E % | M % | H % |
|---|---|---|---|---|---|---|---|
| VAULT II at Georgia Tech | 2026-01-24 | ✓ | 4 | 25.00 | 100% | 100% | 50% |
| Triangle Cup | 2026-03-13 | ✓ | 3 | 13.33 | 100% | 0% | 33% |
| VAULT II at Eden Prairie HS | 2026-03-13 | ✓ | 3 | 13.33 | 100% | 33% | 0% |
| VAULT II at McGill | 2026-03-13 | ✓ | 2 | 25.00 | 100% | 100% | 50% |
| VAULT II at UCSB | 2026-03-13 | ✓ | 4 | 10.00 | 100% | 0% | 0% |
| VAULT II Southern UK | 2026-04-24 | ✓ | 1 | 10.00 | 100% | 0% | 0% |
| VAULT II at Harvard | 2026-04-30 | ✓ | 1 | 20.00 | 100% | 100% | 0% |
| VAULT II at MINT | 2026-06-19 | ✓ | 3 | 10.00 | 100% | 0% | 0% |
| VAULT II Stanford Online | 2026-07-17 | ✓ | 7 | 15.71 | 100% | 43% | 14% |